Renji is the lieutenant of the 6th Division in the Gotei 13. His personality constantly changing, sometimes he's conceited and bumptious to restless and oppress but shows himself as strong and decisive.

She is first seen being assigned to escort Orihime to Aizen's room along with Menoly. With Aizen pleased, he dismisses them, however the two seem hesitant as they believe leaving him alone with her might be dangerous due to her powers. Aizen becomes somewhat annoyed, and the two apologize and leave the room angered and jealous of Orihime, while Ulquiorra watches.

She is a boyish-girl, and a real strong one. Since the beginning, she's been extremely close to Orihime. She has a blackbelt in karate and because she was hit by a car, she wouldn't have lost the finals in the Japanese High School Karate tournament. Since she did have the car accident she became runner up instead. She has this aggressive type personality, if shes mad, she can take down an apponent easily with powerful kicks and punchs. Luckily, she is not that bad-tempered and always hangs out with Orihime.

Misuho is a furious, fierce and intense brunette sister of Keigo. She is attracted to men that are bald and quite fashionable.

When Bonnie was just a piglet, she was injured. Luckily Kaien was able to take care of her, and raise her. The ribbon she wears was also given to her by Kaien.

Numb is a very sadistic hollow, always taking pleasure in other peoples misery, especially when she's the one causing the pain. All though she shares that trait with most hollows, she is a little unique when it comes to fighting. She often takes her time picking the fight and will only fight if it's in her favor or if she knows she will win.

Sung-Sun appears to be the most composed, mature, and intelligent of Harribel's Fracción, often advising her fellow Fracción, Apacci and Mila Rose, to stop arguing, as it makes them look weak, then chiding their angry responses. She has a sort of snobbish attitude toward her fellow teammates and complains when they get in her way during combat. She can easily get them riled up by taunting them and putting her hand in their faces as if she's ignoring them.

She is an unknown spirit that hangs around a street lamp. A simple glass with flowers sits by the lamp as a memorial for her.

Riruka comes across as a very confident and somewhat playful person, although at times she can also be impatient and hot-tempered. She claims to be with her group only for her own agenda and not out of any loyalty to Kūgo. She is extremely talkative and likes having an ongoing one-sided conversation about irrelevant topics. She suffers from extreme myopia but avoids wearing glasses out of her vanity and claims contact lenses make her large eyes dry out too fast.

Prior to becoming a Números, Apacci was a deer-like Hollow. Apacci first met Harribel back when she was still an Adjuchas. Harribel saved her from another Hollow that was about to devour her. She then followed Harribel back to her base where she met Franceska Mila Rose and Cyan Sung-Sun. There, Harribel invited Apacci to join their group, but Apacci was resistant to the idea of working in a team. However, she reluctantly agrees.

Kisuke Urahara brought her into the Shinigami Research and Development Institute since it opened and has continued to stay there.

Lilynette can be both cheerful and mischievous at the same time. She enjoys waking Starrk up in very unusual ways, such as shoving her fist down his throat. Despite her initially childish behavior, she does have a more serious side.

Kyōko is a very solitary person who keeps mostly to herself. She's very smart and athletic. She is also very perceptive often being able to predict what will come next in a combat situation.

She is highly mischievous, and tends to get bored rather easily. She enjoys taunting her opponents, and seems to possess a slight sadistic streak (or a more aggressive side to her flirtatious nature), based on her comments about "playing" with Ichigo when she and Tobiume first encountered him a few minutes before their first fight with Momo and Rangiku.

Tier is the blonde, green-eyed Arrancer who is tactical, analytical and self-composed when it comes to facing combat. She can be brutal and truculent when fighting her foes.

Haru is a very caring soft spoken women. She is very kind and tries to help everyone. She met Tōshirō Hitsugaya and started to take care of him when he was sent down to train.

Momo is a dark-haired, brown-eyed Shinigami who loves reading books and painitng. She is describe as optimistic, cheerful, carefree, upbeat and friendly and she has a strong friendship with Tōshirō Hitsugaya, whom she grew up with, repeatedly calling him "Shirō-chan" despite his higher rank and he often complains about this. Though normally kind, her rare bouts of anger can appear rather menacing.

Shinji is the captain of the 5th Division in the Gotei 13. He is somewhat comical, annoying and normally speaks in a Kansai dialect. He loves listening to jazz music.

She appears to be attracted to Orihime Inoue who she calls "Hime," meaning princess. She hugs Orihime every chance she gets, and usually compliments her and fondles her chest. Chizuru also makes advances toward Michiru Ogawa. She is usually stopped by Tatsuki who always hits her to get her off Orihime, but if anyone else interferes or says anything negative about Orihime, she goes into a rage.

Orihime is a student at the Karakura High School and the classmate of Ichigo. Very naive and clueless, she excels in her studies and is seen as independent, caring and comical. Orihime has a crush on Ichigo and suddenly falls in love with him and can able to smell him.

Kanisawa is a brunette student at the Shinō Academy where she was practicing how to kill the Hollow. She was killed by a Huge Hollow when Hisagi was about to end the training.

Kon is a pervert and engrosses his mind when it comes to sex. He is taking advantage of hugging girls between their breast which is his favorite part of a girl's body. Kon's appearance is a combination of a teddy bear and a stuff lion.

Isane is generally quiet and observant, with a strong sense of loyalty. She can be impatient in the face of an enemy, rushing after enemies she has no chance of defeating. She also looks to Unohana as a mentor and mother figure.

Kiyone is the younger sister of Isane Kotetsu, the Lieutenant of the Fourth Division. Unlike her sister, Kiyone is very open and excitable but she does share Isane's sense of loyalty. She holds her captain, Jūshirō Ukitake, in high regard and always tries to impress him in any way possible, even if she has to ruin her partner Sentarō Kotsubaki to do so.

Byakuya is the 28th head of their clan, Kuchiki. He acts in a noble way and is seen somewhat kind of unconcerned and tranquil.

Hisana is a kind, caring and loving woman. she is very soft-spoken, and also didn't speak too often. Hisana felt very guilty for leaving Rukia behind to save herself, feeling that she didn't deserve to be called her sister. She loved Rukia greatly, but could not care for the both of them.

Soul Reaper Rukia is in the 13th Division under Jūshirō Ukitake. Shortly after meeting the main protagonist of the series, Ichigo Kurosaki, who can see supernatural beings such as Soul Reapers, she is forced to give him some of her powers in order to fulfill her duties as a Soul Reaper.

Seigen Suzunami adopted Matsuri into his noble family. She is a very hard working individual and often critisizes Fujimaru when she isn't being serious at her work.

Nozomi has quite a defensive personality and she is also very independent. However, when Ichigo and his friends open up to her, she is revealed to have more of an exuberant personality. She was created during Project Spearhead, the project that created the modified souls. She was the first Mod Soul created during the project.

Mashiro has very childish and immature mannerisms. She is portrayed as rather flighty and rarely takes note of the bigger picture around her. She is prone to throwing fits over the smallest of things.

Ryō is very athletic as she is the first year track and feild star. She also loves books, often carrying one with her wherever she goes. She also ranked second in her grade on the school exams.

Yuzu is the youger sister of Ichigo and twin sister of Karin. Unlike Karin, she's a bit more girlish and shows more empathy and speaks gently.

Ichigo is a half-Human and half-Shinigami. Despite being a ridiculous guy with orange hair, he is shown to be very complex, strong-minded, hot-tempered and impulsive and retaining his image of being cool even though what other people people say to him. Ichigo's good looks doesn't interfere with his studies since he was rank in the 23rd place at his school and always do his assignments at home and gets good grades.

Karin is the younger sister of Ichigo and the twin sister of Yuzu. Unike Yuzu, she often seen wearing masculine clothes like t-shirts, shorts, and cargo pants.

Masaki is the caring and kind-hearted mother of Ichigo who was killed by a Hollow while trying to protect her son from him.

Nemu is a very shy and introverted individual, preferring to stay silent in her captain's presence. Despite Mayuri's seemingly lack of care for her existence she is very loyal to him. She is so loyal that she is willing to badly injure herself just to give him an advantage in battle.

Yachiru has short pink hair and and is quite small. She likes to give the people many nicknames like Ichi for Ichigo. She is usually found behind Kenpachi holding on to his shoulder. Yachiru is very cheerful, energetic, upbeat, and can sometimes be very intimidating when she needs to be.

The taller half of Katen Kyōkotsu is shown to be soft-spoken and composed individual. At the same time, she is shown to have a slight mischievous side, enjoying to humiliate Shunsui. Similar to her partner, she enjoys sake and prefers not to do work whenever possible. The masked half is shown to be a silent and serious individual, who only focuses on the situation at hand. She enters a state of battle readiness whenever somebody calls out from behind her.

Menoly is shy, rational and passive. She is easily manipulated by Loly and will follow most, if not all of her orders with barly any if not any opposition. Menoly rarely speaks her mind and even when doing so, upon being argued back or assaulted as a response, she tends to lower her voice and stay quiet.

Rangiku tends to be a bit of a slacker who dislikes paperwork and loves to drink. She is not the slightest bit modest about her appearance, frequently referring or complaining about her large breasts in normal casual conversation, much to the embarrassment/amusement of anyone around at the time..